Catalytic dechlorination of chlorobenzene in water by Pd/Fe bimetallic system.
In: Journal of Environmental Sciences (IOS Press), Jg. 15 (2003-09-01), Heft 5, S. 647-651
Online
academicJournal
Zugriff:
Catalytic reductive dechlorination of monochlorobenzene(MCB) was carried out in the palladium/iron system. With low Pd loading (0.005%), 45% dechlorination efficiency was achieved with 5 h. Pd as catalyst accelerated the reductive dechlorination reaction. Dechlorination mechanism and kinetics were discussed. The reaction took place on the bimetal surface in a pseudo-first-order reaction, with the rate constant being 0.0071 min[sub-1] (K[subSA] + 8.0 × 10[sup-3] L/ (m[sup2] h). The reduction product for MCB was benezene. [ABSTRACT FROM AUTHOR]
| Titel: |
Catalytic dechlorination of chlorobenzene in water by Pd/Fe bimetallic system.
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| Autor/in / Beteiligte Person: | Zhou Hong-yi, Gh. F. ; Xin-hua, Xu ; Da-hui, Wang |
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| Zeitschrift: | Journal of Environmental Sciences (IOS Press), Jg. 15 (2003-09-01), Heft 5, S. 647-651 |
| Veröffentlichung: | 2003 |
| Medientyp: | academicJournal |
| ISSN: | 1001-0742 (print) |
| DOI: | 1001-0742(2003)05-0647-05 |
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