Martian CO<subscript>2</subscript> Ice Observation at High Spectral Resolution With ExoMars/TGO NOMAD.

The Nadir and Occultation for MArs Discovery (NOMAD) instrument suite aboard ExoMars/Trace Gas Orbiter spacecraft is mainly conceived for the study of minor atmospheric species, but it also offers the opportunity to investigate surface composition and aerosols properties. We investigate the information content of the Limb, Nadir, and Occultation (LNO) infrared channel of NOMAD and demonstrate how spectral orders 169, 189, and 190 can be exploited to detect surface CO2 ice. We study the strong CO2 ice absorption band at 2.7 μm and the shallower band at 2.35 μm taking advantage of observations across Martian Years 34 and 35 (March 2018 to February 2020), straddling a global dust storm. We obtain latitudinal‐seasonal maps for CO2 ice in both polar regions, in overall agreement with predictions by a general climate model and with the Mars Express/OMEGA spectrometer Martian Years 27 and 28 observations. We find that the narrow 2.35 μm absorption band, spectrally well covered by LNO order 189, offers the most promising potential for the retrieval of CO2 ice microphysical properties. Occurrences of CO2 ice spectra are also detected at low latitudes and we discuss about their interpretation as daytime high altitude CO2 ice clouds as opposed to surface frost. We find that the clouds hypothesis is preferable on the basis of surface temperature, local time and grain size considerations, resulting in the first detection of CO2 ice clouds through the study of this spectral range. Through radiative transfer considerations on these detections we find that the 2.35 μm absorption feature of CO2 ice clouds is possibly sensitive to nm‐sized ice grains. Plain Language Summary: The Nadir and Occultation for MArs Discovery (NOMAD) instrument aboard the ExoMars/Trace Gas Orbiter spacecraft is conceived for the study of non‐abundant gaseous species in the atmosphere of Mars. Nevertheless, we investigate its capability to observe the Martian surface, suspended dust and CO2 ice clouds. We verify that part of the signal registered by the instrument contains information on the presence of CO2 ice on the surface of Mars. We produce maps that predict the seasonal condensation/sublimation of the ice that are in general good agreement with a Mars climate model and with observations acquired by the OMEGA instrument aboard the Mars Express spacecraft. The data we study also observed a dust storm that globally enveloped the planet in 2018, allowing us to deduce that the dust in the atmosphere strongly affects the capability to detect the ice on the surface. Finally, we also find that some observations are compatible with CO2 ice clouds made of extremely small crystals (dimensions of some millionths of millimeters) that have never been observed by studying such specific part of the signal registered by NOMAD. Key Points: Martian surface CO2 ice detection at high spectral resolution with Trace Gas Orbiter/Nadir and Occultation for MArs DiscoveryGeneral good agreement of the seasonal surface CO2 ice maps with Mars Express/OMEGA observations and with Mars Climate Database predictionsCO2 ice clouds detection through the 2.35 micron CO2 ice absorption band, likely sensitive to a population of nm‐sized ice grains [ABSTRACT FROM AUTHOR]