Volltext verfügbar nach Anmeldung bzw. im Campus-Netz.
United in Nitride: The Highly Condensed Boron Phosphorus Nitride BP<subscript>3</subscript>N<subscript>6</subscript>.
In: Angewandte Chemie, Jg. 130 (2018-10-01), Heft 40, S. 13386-13389
Online
academicJournal
Zugriff:
Abstract: Owing to intriguing materials properties non‐metal nitrides are of special interest for both, solid‐state chemistry and materials science. Mixed ternary non‐metal nitrides, however, have only been sparsely investigated, as preparative chemistry lacks a systematic access, yet. Herein, we report on the highly condensed boron phosphorus nitride BP3N6, which was synthesized from (PNCl2)3, NH4N3 and h‐BN in a high‐pressure high‐temperature reaction. By increasing partial pressure of HCl during synthesis using NH4Cl, single‐crystals of BP3N6 up to 80 μm in length were obtained. The unprecedented framework‐type structure determined by single‐crystal XRD blends structural motifs of both, α‐P3N5 and c‐BN, rendering BP3N6 a double nitride. The compound was further investigated by Rietveld refinement, EDX, temperature‐dependent PXRD, FTIR and solid‐state NMR spectroscopy. The formation of BP3N6 through use of reactive precursors exemplifies an innovative access to mixed non‐metal nitrides. [ABSTRACT FROM AUTHOR]
Titel: |
United in Nitride: The Highly Condensed Boron Phosphorus Nitride BP<subscript>3</subscript>N<subscript>6</subscript>.
|
---|---|
Autor/in / Beteiligte Person: | Vogel, Sebastian ; Buda, Amalina T. ; Schnick, Wolfgang |
Link: | |
Zeitschrift: | Angewandte Chemie, Jg. 130 (2018-10-01), Heft 40, S. 13386-13389 |
Veröffentlichung: | 2018 |
Medientyp: | academicJournal |
ISSN: | 0044-8249 (print) |
DOI: | 10.1002/ange.201808111 |
Schlagwort: |
|
Sonstiges: |
|