Synthesis of ferrocenoyl amino acid derivatives via homogeneous catalytic aminocarbonylation
In: Journal of Organometallic Chemistry, Jg. 690 (2005-07-01), Heft 13, S. 3237-3242
academicJournal
Zugriff:
Abstract: Palladium-catalysed aminocarbonylation of iodoferrocene with amino acid esters as nucleophiles results in the selective formation of N-ferrocenoyl amino acid esters in the presence of Et3N as the base. At the same time, the use of DBU leads to the formation of new N-ferrocenylglyoxyl amino acid derivatives with reasonable selectivity. In the latter reactions two new side products, formed via acylation of DBU, were also isolated and characterised. [Copyright &y& Elsevier]
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Synthesis of ferrocenoyl amino acid derivatives via homogeneous catalytic aminocarbonylation
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Autor/in / Beteiligte Person: | Kuik, Árpád ; Skoda-Földes, Rita ; Balogh, János ; Kollár, László |
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Zeitschrift: | Journal of Organometallic Chemistry, Jg. 690 (2005-07-01), Heft 13, S. 3237-3242 |
Veröffentlichung: | 2005 |
Medientyp: | academicJournal |
ISSN: | 0022-328X (print) |
DOI: | 10.1016/j.jorganchem.2005.03.054 |
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