Synthesis and structural characterization of zinc complexes supported by amino-benzotriazole phenoxide ligands: Efficient catalysts for ring-opening polymerization of ε-caprolactone and β-butyrolactone
In: Inorganic Chemistry Communications, Jg. 14 (2011-07-01), Heft 7, S. 1140-1144
academicJournal
Zugriff:
Abstract: Two amino-benzotriazole phenol ligands, 2-(2H-benzotriazol-2-yl)-6-((diethylamino)methyl)-4-alkyl-phenol (alkyl=CH3, C1DEA BTP-H, and alkyl=C8H17, C8DEA BTP-H) were prepared through the Mannich condensation of 4-alkyl-2-(2H-benzotriazol-2-yl)phenol with the mixtures of excess paraformaldehyde and diethylamine under reflux conditions. Zinc complexes supported by amino-benzotriazole phenoxide ligands ( C1DEA BTP − and C8DEA BTP −) were synthesized and fully characterized. The reaction of ZnEt2 with DEA BTP-H (1equiv.) produces the tetra-coordinated dimeric zinc complexes [(μ- C1DEA BTP)ZnEt]2 (1) and [(μ- C8DEA BTP)ZnEt]2 (2). Experimental results indicate that complex 1 catalyzes the ring-opening polymerization of ε-caprolactone and β-butyrolactone with good catalytic activities in a controlled character. [Copyright &y& Elsevier]
Titel: |
Synthesis and structural characterization of zinc complexes supported by amino-benzotriazole phenoxide ligands: Efficient catalysts for ring-opening polymerization of ε-caprolactone and β-butyrolactone
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Autor/in / Beteiligte Person: | Li, Jia-Ying ; Li, Chen-Yu ; Tai, Wan-Ju ; Lin, Chia-Her ; Ko, Bao-Tsan |
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Zeitschrift: | Inorganic Chemistry Communications, Jg. 14 (2011-07-01), Heft 7, S. 1140-1144 |
Veröffentlichung: | 2011 |
Medientyp: | academicJournal |
ISSN: | 1387-7003 (print) |
DOI: | 10.1016/j.inoche.2011.04.008 |
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