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Synthesis and Crystal Structure of a Novel Copper(II) Complex Derived from N,N'-Bis(3-ethoxysalicylidene)-1,2-ethanediamine.
In: Synthesis & Reactivity in Inorganic, Metal-Organic, Jg. 41 (2011-08-01), Heft 7, S. 750-753
Online
academicJournal
Zugriff:
A novel mononuclear copper(II) complex, [CuL]2·C2 H10N2·2ClO4 (H2L = N,N'-bis(3-ethoxysalicylidene)-1,2-ethanediamine), has been synthesized and characterized by elemental analysis and single-crystal x-ray diffraction. The compound consists of two mononuclear copper(II) complex molecules, two perchlorate anions, and one protonated ethane-1,2-diamine molecule that bridges adjacent two copper(II) complex molecules through hydrogen bonds. The CuII atom is four-coordinate in a square-planar geometry, with two imino N and two phenolic O atoms of the Schiff base ligand. [ABSTRACT FROM AUTHOR]
Titel: |
Synthesis and Crystal Structure of a Novel Copper(II) Complex Derived from N,N'-Bis(3-ethoxysalicylidene)-1,2-ethanediamine.
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Autor/in / Beteiligte Person: | Cui, Yong-Ming ; Hou, Peng ; You, Zhong-Lu |
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Zeitschrift: | Synthesis & Reactivity in Inorganic, Metal-Organic, Jg. 41 (2011-08-01), Heft 7, S. 750-753 |
Veröffentlichung: | 2011 |
Medientyp: | academicJournal |
ISSN: | 1553-3174 (print) |
DOI: | 10.1080/15533174.2011.591299 |
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