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Isolation and Properties of a Chain of Cyano-Bridged Complex {LCu ( μ -CN)} n With Triazenido Ligand and a Cyano-Bridged Mixed-Valence Complex {Cu Cu ( μ -CN) 3 } n.
In: Synthesis & Reactivity in Inorganic, Metal-Organic, Jg. 42 (2012-11-01), Heft 10, S. 1375-1380
Online
academicJournal
Zugriff:
One reaction of 1-[(2-carboxymethyl) benzene]-3-[2-pyridine] triazene (HL) with CuCl2·2H2O, and NaCN gives a chain of cyano-bridged complex {LCuII(μ-CN)}n 1 and a cyano-bridged mixed-valence complex {CuIICuI(μ-CN)3}n 2, respectively. The X-ray crystal structures of both complexes have been obtained. Magnetic studies indicate significant antiferromagnetic coupling between the copper(II) centers for complex 1, with coupling constants (J) of –129.6 cm−1. [ABSTRACT FROM AUTHOR]
| Titel: |
Isolation and Properties of a Chain of Cyano-Bridged Complex {LCu ( μ -CN)} n With Triazenido Ligand and a Cyano-Bridged Mixed-Valence Complex {Cu Cu ( μ -CN) 3 } n.
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| Autor/in / Beteiligte Person: | Jian, Wan-Yuan ; Li, Wei ; Lv, Qi-Ying ; Min, Xin ; Liu, Yue-Yun ; Zhan, Shu-Zhong |
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| Zeitschrift: | Synthesis & Reactivity in Inorganic, Metal-Organic, Jg. 42 (2012-11-01), Heft 10, S. 1375-1380 |
| Veröffentlichung: | 2012 |
| Medientyp: | academicJournal |
| ISSN: | 1553-3174 (print) |
| DOI: | 10.1080/15533174.2012.680147 |
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