Ion and water mobility in hydrated Li-LSX zeolite studied by <superscript>1</superscript>H, <superscript>6</superscript>Li and <superscript>7</superscript>Li NMR spectroscopy and diffusometry
In: Microporous & Mesoporous Materials, Jg. 172 (2013-05-15), S. 174-181
academicJournal
Zugriff:
Abstract: Crystallites of zeolite LSX with a diameter of about 10μm were synthesized. Crystals of this size are shown to allow the simultaneous investigation of intracrystalline mass transfer phenomena of water molecules and lithium ions in hydrated zeolite Li-LSX by NMR diffusometry. By MAS NMR spectroscopy with the 1H and 6Li nuclei, the water molecules and lithium ions are found to yield two signals, a major and a minor one, which may be attributed to locations in the sodalite cages and the supercages, respectively. By 1H and 6Li exchange spectroscopy the mean residence times in the sodalite cages at 373K are found to be about 150ms for the water molecules and about 40ms for the lithium cations. PFG NMR self-diffusion measurements at 373K yield a diffusivity of about 2×10−11 m2 s−1 for the lithium ions, which is about one order of magnitude below the water diffusivity. [Copyright &y& Elsevier]
| Titel: |
Ion and water mobility in hydrated Li-LSX zeolite studied by <superscript>1</superscript>H, <superscript>6</superscript>Li and <superscript>7</superscript>Li NMR spectroscopy and diffusometry
|
|---|---|
| Autor/in / Beteiligte Person: | Freude, D. ; Beckert, S. ; Stallmach, F. ; Kurzhals, R. ; Täschner, D. ; Toufar, H. ; Kärger, J. ; Haase, J. |
| Link: | |
| Zeitschrift: | Microporous & Mesoporous Materials, Jg. 172 (2013-05-15), S. 174-181 |
| Veröffentlichung: | 2013 |
| Medientyp: | academicJournal |
| ISSN: | 1387-1811 (print) |
| DOI: | 10.1016/j.micromeso.2013.01.011 |
| Schlagwort: |
|
| Sonstiges: |
|