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Magnetic molecularly imprinted polymers (MMIPs) are constructed based on the blending of inorganic nanoparticles with molecularly imprinted polymers (MIPs). MMIPs are synthesized in a core-shell format in which inorganic nanoparticles are applied as the core part of the material while selective polymeric layers are used as the shell covering the surface of the core area. In essence, MMIPs thus reflect a combination of the best characteristics of both inorganic nanoparticles and MIPs, where the specificity of cavities imprinted on the MIP is merged with superparamagnetic properties of the nano-magnetite. The synergic combination of the two distinct materials facilitates the process of extracting analytes from complex samples. Owing to their suitable characteristics, MMIPs have become widely used in different areas of analysis.

Titel:	Magnetic MIPs: Synthesis and Applications.
Autor/in / Beteiligte Person:	da Fonseca Alves R ; da Silva LNC ; Matos Neto, G ; Ierick, IF ; Ferreira, TL ; Sotomayor, MDPT
Zeitschrift:	Methods in molecular biology (Clifton, N.J.), Jg. 2359 (2021), S. 85-96
Veröffentlichung:	Totowa, NJ : Humana Press ; <i>Original Publication</i>: Clifton, N.J. : Humana Press,, 2021
Medientyp:	academicJournal
ISSN:	1940-6029 (electronic)
DOI:	10.1007/978-1-0716-1629-1_7
Schlagwort:	Adsorption Magnetic Phenomena Magnetics Magnetite Nanoparticles Molecularly Imprinted Polymers Polymers Molecular Imprinting
Sonstiges:	Nachgewiesen in: MEDLINE Sprachen: English Publication Type: Journal Article; Research Support, Non-U.S. Gov't Language: English [Methods Mol Biol] 2021; Vol. 2359, pp. 85-96. MeSH Terms: Molecular Imprinting* ; Adsorption ; Magnetic Phenomena ; Magnetics ; Magnetite Nanoparticles ; Molecularly Imprinted Polymers ; Polymers References: Pupin RR (2017) Nanomagnetic biomimetic polymers with restricted access (magnetic RAMIP) obtained by semicovalent and non-covalent synthesis for application in immunosensors and immunoassays. Dissertation, State University of São Paulo. ; Khan S, Hussain S, Wong A, Foguel MV, Moreira Gonçalves L, Pividori Gurgo MI, Taboada Sotomayor M d P (2018) Synthesis and characterization of magnetic-molecularly imprinted polymers for the HPLC-UV analysis of ametryn. React Funct Polym 122:175–182. https://doi.org/10.1016/j.reactfunctpolym.2017.11.002. (PMID: 10.1016/j.reactfunctpolym.2017.11.002) ; Silva LM (2018) Synthesis, characterization and optimization of selective MIP-magnetic to ciprofloxacin and evaluation of the viability of the simultaneous use of two functional monomers. State University of São Paulo. ; Ruiz-Córdova GA, Khan S, Gonçalves LM, Pividori MI, Picasso G, Sotomayor MDPT (2018) Electrochemical sensing using magnetic molecularly imprinted polymer particles previously captured by a magneto-sensor. Talanta 181:19–23. https://doi.org/10.1016/j.talanta.2017.12.085. (PMID: 10.1016/j.talanta.2017.12.085) ; Hanwell MD, Curtis DE, Lonie DC, Vandermeersch T, Zurek E, Hutchison GR (2012) Avogadro: An advanced semantic chemical editor, visualization, and analysis platform. J Cheminform 4:17. (PMID: 10.1186/1758-2946-4-17) ; Humphrey W, Dalke A, Schulten K (1996) VMD – visual molecular dynamics. J Mol Graph 14:33–38. (PMID: 10.1016/0263-7855(96)00018-5) ; Zhang IY, Wu J, Xu X (2010) Extending the reliability and applicability of B3LYP. Chem Commun 46:3057–3070. https://doi.org/10.1039/c000677g. (PMID: 10.1039/c000677g) ; Nkurikiyimfura I, Wang Y, Safari B, Nshingabigwi E (2020) Temperature-dependent magnetic properties of magnetite nanoparticles synthesized via coprecipitation method. J Alloys Compd 846:156344. https://doi.org/10.1016/j.jallcom.2020.156344. (PMID: 10.1016/j.jallcom.2020.156344) ; Allouche A (2012) Software news and updates gabedit—A graphical user interface for computational chemistry softwares. J Comput Chem 32:174–182. https://doi.org/10.1002/jcc. (PMID: 10.1002/jcc) ; Frisch MJ, Trucks GW, Schlegel HB, Scuseria GE, Robb MA, Cheeseman JR, Scalmani G, Barone V, Petersson GA, Nakatsuji HX, Li MC, Marenich A, Bloino J, Janesko BG, Gomperts R, Mennucci B, Hratchian HP, Ortiz JV, Izmaylov AF (2016) Gaussian 09. Revis. A.02. Gaussian Inc., Wallingford CT. ; Fabian MD, Shpiro B, Rabani E, Neuhauser D, Baer R (2019) Stochastic density functional theory. Wiley Interdiscip Rev Comput Mol Sci 9:1–15. https://doi.org/10.1002/wcms.1412. (PMID: 10.1002/wcms.1412) ; Neese F (2012) The ORCA program system. Wiley Interdiscip Rev Comput Mol Sci 2:73–78. https://doi.org/10.1002/wcms.81. (PMID: 10.1002/wcms.81) ; Schmidt MW, Baldridge KK, Boatz JA, Elbert ST, Gordon MS, Jensen JH, Koseki S, Matsunaga N, Nguyen KA, Su S, Windus TL, Dupuis M, Montgomery JA (1993) General atomic and molecular electronic structure system. J Comput Chem 14:1347–1363. https://doi.org/10.1002/jcc.540141112. (PMID: 10.1002/jcc.540141112) Contributed Indexing: Keywords: Electrochemistry; Magnetic molecular imprinted polymer; Magnetic nanoparticles; Molecularly imprinted polymers; Solid-Phase Extraction Substance Nomenclature: 0 (Magnetite Nanoparticles) ; 0 (Molecularly Imprinted Polymers) ; 0 (Polymers) Entry Date(s): Date Created: 20210819 Date Completed: 20220103 Latest Revision: 20220103 Update Code: 20231215

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Magnetic MIPs: Synthesis and Applications.