Mechanochemical synthesis of fluoride-ion conducting glass and glass-ceramic in ZrF <subscript>4</subscript> -BaF <subscript>2</subscript> binary system.
In: Scientific reports, Jg. 14 (2024-04-16), Heft 1, S. 8808
Online
academicJournal
Zugriff:
Fluoride glasses in the binary system ZrF 4 -BaF 2 were prepared via mechanochemical treatment. The glass-forming region of the ZrF 4 -BaF 2 system obtained using the mechanochemical method was wider than that obtained using the conventional melt-quenching method. The glass-ceramic 60ZrF 4 ·40BaF 2 (mol%) sample was obtained by heat treatment and shows a higher conductivity of 1.2 × 10 -6 S cm -1 at 200 °C than the pristine glass. This study revealed that mechanochemical treatment was effective for the synthesis of fluoride glasses.
(© 2024. The Author(s).)
Titel: |
Mechanochemical synthesis of fluoride-ion conducting glass and glass-ceramic in ZrF <subscript>4</subscript> -BaF <subscript>2</subscript> binary system.
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Autor/in / Beteiligte Person: | Motohashi, K ; Higuchi, H ; Nakajima, H ; Mori, S ; Sakuda, A ; Hayashi, A |
Link: | |
Zeitschrift: | Scientific reports, Jg. 14 (2024-04-16), Heft 1, S. 8808 |
Veröffentlichung: | London : Nature Publishing Group, copyright 2011-, 2024 |
Medientyp: | academicJournal |
ISSN: | 2045-2322 (electronic) |
DOI: | 10.1038/s41598-024-59040-4 |
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