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Synthesis, crystal structure, and spectroscopic properties of CuL [H 2 L=2,3-dioxo-5,6:13,14-dichlorobenzo-7,12-diphenyl-1,4,8,11-tetra-azacyclo-pentadeca-7,11-diene] and [(LCu)Cu(phen)(EtOH)](ClO 4 ) 2 · EtOH · 0.25H 2 O: from mono- to dinuclear complex
In: Journal of Coordination Chemistry, Jg. 59 (2006-07-10), Heft 10, S. 1183-1189
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Zugriff:
Based on the complex ligand CuL (H 2 L = 2,3-dioxo-5,6:13,14-dichlorobenzo-7,12-diphenyl-1,4,8,11-tetraazacyclo-pentadeca-7,11-diene) (1), a dinuclear complex [(LCu)Cu(phen)(EtOH)](ClO 4 ) 2 · EtOH · 0.25H 2 O (2) was prepared. The crystal structures of 1 and 2 have been determined. IR, electronic and EPR spectra are discussed. [ABSTRACT FROM AUTHOR]
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Titel: |
Synthesis, crystal structure, and spectroscopic properties of CuL [H 2 L=2,3-dioxo-5,6:13,14-dichlorobenzo-7,12-diphenyl-1,4,8,11-tetra-azacyclo-pentadeca-7,11-diene] and [(LCu)Cu(phen)(EtOH)](ClO 4 ) 2 · EtOH · 0.25H 2 O: from mono- to dinuclear complex
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Autor/in / Beteiligte Person: | Zhang, Rui-Hong ; Wang, Qing-Lun ; Yang, Guang-Ming |
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Zeitschrift: | Journal of Coordination Chemistry, Jg. 59 (2006-07-10), Heft 10, S. 1183-1189 |
Veröffentlichung: | 2006 |
Medientyp: | academicJournal |
ISSN: | 0095-8972 (print) |
DOI: | 10.1080/00958970500490673 |
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