Crystal structure and magnetic properties of a three-dimensional complex constructed from [CuL]<superscript>2</superscript> and [Fe(CN)<subscript>6</subscript>]<superscript>3â</superscript> precursors.
In: Transition Metal Chemistry, Jg. 33 (2008-02-15), Heft 1, S. 133-136
Online
academicJournal
Zugriff:
Abstract  Self-assembly of the precursor [Cu(L)]2 (L = 3,10-dipropyl-1,3,5,8,10,12-hexaazacyclotetradecane) with hexacyanometalate [Fe(CN)6]3â produces a 3-D cyano-bridged Cu(II)âFe(III) bimetallic assembly, [CuL]2[Fe(CN)6]ClO4 · H2O (1), characterized by single-crystal X-ray diffraction studies, and magnetic measurements. The crystallographic determination reveals that each hexacyanoferromate(III) ion connects four copper(II) ions using four co-planar CNâ groups which axially coordinate to the copper ion in a trans fashion forming trans-CuL(Nâ¡C)2 moieties in (1). Magnetic studies reveal that (1) displays a ferromagnetic interaction between Cu(II) and Fe(III) through the CN linkage. [ABSTRACT FROM AUTHOR]
Copyright of Transition Metal Chemistry is the property of Springer Nature and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Titel: |
Crystal structure and magnetic properties of a three-dimensional complex constructed from [CuL]<superscript>2</superscript> and [Fe(CN)<subscript>6</subscript>]<superscript>3â</superscript> precursors.
|
---|---|
Autor/in / Beteiligte Person: | Yuan, Ai-hua ; Shen, Xiao-ping ; Zhou, Hu |
Link: | |
Zeitschrift: | Transition Metal Chemistry, Jg. 33 (2008-02-15), Heft 1, S. 133-136 |
Veröffentlichung: | 2008 |
Medientyp: | academicJournal |
ISSN: | 0340-4285 (print) |
DOI: | 10.1007/s11243-007-9032-0 |
Sonstiges: |
|