Synthesis, Crystal Structures and Fluorescence Properties of Ni (II) and Cu (II) Complexes with 1-(Furan-2-ylmethylene)-4-phenylthiosemicarbazone.
In: Journal of Chemical Crystallography, Jg. 40 (2010), Heft 1, S. 4-9
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Zugriff:
Abstract  Two coordination complexes, NiL 2 and CuL 2 {L = bis[1-(furan-2-ylmethylene)-4-phenylthiosemicarbazone]}, were synthesized and determined by X-ray crystallography. Both crystallize in the Orthorhombic system, space group Pbcn, with lattice parameters: a = 11.935 (2) â«, b = 15.314(3) â«, c = 12.952(3) ⫠and Z = 4 for Ni (II); a = 20.850(4) â«, b = 15.049(3) â«, c = 7.5633(5) ⫠and Z = 4 for Cu (II). In both complexes, the central metal atom is coordinated in a distorted square-planar with two ligands through two S and N atoms, respectively. The EA, UV, IR and TG-DTG were studied and the possible structures of the complexes were speculated. Moreover, the fluorescence of the complexes were studied. The results reveal that copper complex can emit purple fluorescence in solvents. Graphical Abstract  Two coordination complexes, NiL2 and CuL2 {L = bis[1-(furan-2-ylmethylene)-4-phenylthiosemicarbazone]}, were synthesized and determined by X-ray crystallography. In both complexes, the central metal atom is coordinated in a distorted square-planar with two ligands L through two S and N atoms, respectively. [ABSTRACT FROM AUTHOR]
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Titel: |
Synthesis, Crystal Structures and Fluorescence Properties of Ni (II) and Cu (II) Complexes with 1-(Furan-2-ylmethylene)-4-phenylthiosemicarbazone.
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Autor/in / Beteiligte Person: | Sun, Ping ; Jian, Fang ; Wang, Xian |
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Zeitschrift: | Journal of Chemical Crystallography, Jg. 40 (2010), Heft 1, S. 4-9 |
Veröffentlichung: | 2010 |
Medientyp: | academicJournal |
ISSN: | 1074-1542 (print) |
DOI: | 10.1007/s10870-009-9595-z |
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