Transition metal complexes with 2-( N-tosylamino)benzaldehyde 1-phthalazinylhydrazone.
In: Russian Journal of Coordination Chemistry, Jg. 37 (2011-07-01), Heft 7, S. 483-491
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Zugriff:
2-( N-Tosylamino)benzaldehyde 1-phthalazinylhydrazone (HL) and its complexes with Cu(II), Ni(II), and Mn(II) were obtained. The acid-basic properties of the hydrazone were studied using potentiometry and spectrophotometry. The experimental data were compared with the results of quantum-chemical DFT calculations. The structure of the binuclear complex [CuL] was determined using X-ray diffraction. The broken symmetry approach was used to calculate the exchange coupling constant of the copper ions. [ABSTRACT FROM AUTHOR]
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Titel: |
Transition metal complexes with 2-( N-tosylamino)benzaldehyde 1-phthalazinylhydrazone.
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Autor/in / Beteiligte Person: | Popov, L. ; Shcherbakov, I. ; Levchenkov, S. ; Tupolova, Yu. ; Burlov, A. ; Aleksandrov, G. ; Lukov, V. ; Kogan, V. |
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Zeitschrift: | Russian Journal of Coordination Chemistry, Jg. 37 (2011-07-01), Heft 7, S. 483-491 |
Veröffentlichung: | 2011 |
Medientyp: | academicJournal |
ISSN: | 1070-3284 (print) |
DOI: | 10.1134/S1070328411060078 |
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