Efficiency of DBU/iodine cooperative dual catalysis for the solvent-free synthesis of five-membered cyclic carbonates under atmospheric CO2 pressure.
In: Journal of CO2 Utilization, Jg. 10 (2015-06-01), S. 7-11
academicJournal
Zugriff:
The DBU·I 2 dual catalyst is shown to have a very high activity for the coupling reaction of CO 2 and various (bis)oxiranes. The cooperative work of both DBU and iodine is tolerant to water and allows performing the cyclo-addition of carbon dioxide in very mild conditions of pressure ( p CO 2 = 1 bar) and in total absence of organic solvent. [ABSTRACT FROM AUTHOR]
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| Titel: |
Efficiency of DBU/iodine cooperative dual catalysis for the solvent-free synthesis of five-membered cyclic carbonates under atmospheric CO2 pressure.
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| Autor/in / Beteiligte Person: | Coulembier, Olivier ; Moins, Sébastien ; Dubois, Philippe ; Lemaur, Vincent ; Lazzaroni, Roberto |
| Zeitschrift: | Journal of CO2 Utilization, Jg. 10 (2015-06-01), S. 7-11 |
| Veröffentlichung: | 2015 |
| Medientyp: | academicJournal |
| ISSN: | 2212-9820 (print) |
| DOI: | 10.1016/j.jcou.2015.02.002 |
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