Synthesis and Structures of [LCu(I)(SSiiPr3)] (L = triphos, carbene) and Related Compounds
In: Inorganic Chemistry, Jg. 55 (2016-09-19), Heft 18, S. 9173-9177
serialPeriodical
Zugriff:
The mononuclear Cu(I) complexes [LCuI(SSiiPr3)] (L = 1,1,1-tris(diphenylphosphinomethyl)ethane (triphos), 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (IMes)) have been prepared by ligand displacement from [LCuICl] with iPr3SiS–. Both compounds are colorless, diamagnetic species and have been characterized structurally by X-ray crystallography. The compounds [(IMes)Cu(η1κS-SC(O)CH3)] and [(triphos)Cu(η1κS-SC(S)OCH3)] have been prepared in the context of synthesis aimed at [LCu(η1κS-SCOS)] and [LCu(η1κS-SCS2)] complexes, which are intended as synthons toward an analogue of the Mo(μ-OSCO)Cu intermediate proposed as occurring in the catalytic cycle of carbon monoxide dehydrogenase (CODH).
| Titel: |
Synthesis and Structures of [LCu(I)(SSiiPr3)] (L = triphos, carbene) and Related Compounds
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| Autor/in / Beteiligte Person: | Ferrara, Skylar J. ; Wang, Bo ; Haas, Elaine ; Wright LeBlanc, Karry ; Mague, Joel T. ; Donahue, James P. |
| Link: | |
| Zeitschrift: | Inorganic Chemistry, Jg. 55 (2016-09-19), Heft 18, S. 9173-9177 |
| Veröffentlichung: | 2016 |
| Medientyp: | serialPeriodical |
| ISSN: | 0020-1669 (print) ; 1520-510X (print) |
| DOI: | 10.1021/acs.inorgchem.5b02811 |
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