Litharge-derived compounds structurally based on layers of Cl− and Br−-centered tetrahedra: Synthesis and structures of the new representatives of MX(ReO4) family (M=Ba, Pb; X=Cl, Br)
In: Solid State Sciences, Jg. 114 (2021-04-01), S. 106576-106576
Online
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Zugriff:
Two new layered barium perrhenate halides, BaX(ReO4) (X = Cl and Br), were prepared and their structures were refined from single-crystal and powder data, respectively. Both compounds are isostructural to the previously reported BaCl(MnO4), exhibiting a matlockite (PbFCl)-derived motif. The structure of previously reported PbBr(ReO4) was also refined, in order to obtain a complete data set; it is similar to PbCl(ReO4). The structures of Ba and Pb compounds correspond to the centro- and non-centrosymmetric versions (pseudo-polymorphs) of the same motif corresponding to the alternation of [M2X2]2+ litharge-derived slabs and double sheets of perrhenate anions. Strong relationships exist to the structures of LnX(TO4) (X = Cl, Br; T = Mo, W) which are monoclinically distorted versions of the orthorhombic permanganates and perrhenates. Crystal chemistry and further perspectives of the compounds with litharge slabs constructed of Cl, Br, and I-centered tetrahedra are discussed.
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Litharge-derived compounds structurally based on layers of Cl− and Br−-centered tetrahedra: Synthesis and structures of the new representatives of MX(ReO4) family (M=Ba, Pb; X=Cl, Br)
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Autor/in / Beteiligte Person: | Borisov, Artem S. ; Plokhikh, Igor V. ; Siidra, Oleg I. ; Markovski, Mishel R. ; Charkin, Dmitri O. |
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Zeitschrift: | Solid State Sciences, Jg. 114 (2021-04-01), S. 106576-106576 |
Veröffentlichung: | Elsevier BV, 2021 |
Medientyp: | unknown |
ISSN: | 1293-2558 (print) |
DOI: | 10.1016/j.solidstatesciences.2021.106576 |
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