A two-dimensional network: poly[aqua-μ2-1,4-diazabicyclo[2.2.2]octane-μ2-terephthalato-zinc(II)]
In: Acta Crystallographica Section E Structure Reports Online, Jg. 62 (2006-08-16), S. m2224- (3S.)
Online
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Zugriff:
In the title complex, [Zn(tp)(dbo)(H2O)]n, where tp is terephthalate (C8H4O4) and dbo is 1,4-diazabicyclo[2.2.2]octane (C6H12N2), each ZnII atom is coordinated by three O atoms from two bis-monodentate tp ligands and one aqua ligand, and by two N atoms from two bridging dbo ligands, in a distorted trigonal–bipyramidal geometry, with the two N atoms located at the axial sites. The bridging tp ligands link the ZnII atoms to form one-dimensional zigzag chains, running along [221]. These chains are assembled into layers parallel to the ac plane by dbo ligands, which are extended into a three-dimensional network by O—H⋯O hydrogen bonds and π–π stacking interactions.
Titel: |
A two-dimensional network: poly[aqua-μ2-1,4-diazabicyclo[2.2.2]octane-μ2-terephthalato-zinc(II)]
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Autor/in / Beteiligte Person: | Sun, Xian-Zhong ; Zhang, Ling-Yun |
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Zeitschrift: | Acta Crystallographica Section E Structure Reports Online, Jg. 62 (2006-08-16), S. m2224- (3S.) |
Veröffentlichung: | International Union of Crystallography (IUCr), 2006 |
Medientyp: | unknown |
ISSN: | 1600-5368 (print) |
DOI: | 10.1107/s1600536806030868 |
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