μ-Oxido-bis{[2,2-bis(3,5-dimethyl-1H-pyrazol-1-yl)acetato-κ3N2,O,N2′]chloridooxidomolybdenum(V)} monohydrate
In: Acta Crystallographica Section E Structure Reports Online, Jg. 66 (2010-11-24), S. m1648- (2S.)
Online
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Zugriff:
In the binuclear title compound, [Mo(2)(C(12)H(15)N(4)O(2))(2)Cl(2)O(3)]·H(2)O, the complex mol-ecules have approximate C(2) symmetry. Both Mo(V) atoms have a distorted octa-hedral coordination environment with cis-positioned terminal chloride and oxide groups. The heteroscorpionate organic ligand binds to the Mo(V) atom via an N(2)O donor set. The water mol-ecule bridges two complex mol-ecules, forming O-H⋯O and O-H⋯Cl hydrogen bonds to the acetate group and to the chloride ligands.
Titel: |
μ-Oxido-bis{[2,2-bis(3,5-dimethyl-1H-pyrazol-1-yl)acetato-κ3N2,O,N2′]chloridooxidomolybdenum(V)} monohydrate
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Autor/in / Beteiligte Person: | Golobič, Amalija ; Čeh, Boris |
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Zeitschrift: | Acta Crystallographica Section E Structure Reports Online, Jg. 66 (2010-11-24), S. m1648- (2S.) |
Veröffentlichung: | International Union of Crystallography (IUCr), 2010 |
Medientyp: | unknown |
ISSN: | 1600-5368 (print) |
DOI: | 10.1107/s1600536810045393 |
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