Polar crystalline phases of PVDF induced by interaction with functionalized boron nitride nanosheets
In: CrystEngComm, Jg. 22 (2020), S. 6207-6215
Online
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Zugriff:
Due to their unique structure and excellent physical properties, boron nitride nanosheets (BNNSs) are often used as nano-reinforcing fillers for polymeric composites. In this work, hydroxyl-modified boron nitride nanosheets (OH-BNNSs) and amino-functionalized boron nitride nanosheets (NH2-BNNSs) were blended with poly(vinylidene fluoride) (PVDF) via a solution casting method to form PVDF/OH-BNNS and PVDF/NH2-BNNS nanocomposites. Differential scanning calorimetry (DSC), wide angle X-ray diffraction (WAXD) and Fourier transform infrared spectroscopy (FTIR) show that the addition of OH-BNNSs has little influence on the crystal structure of PVDF, and non-polar α-crystals are mainly formed in the PVDF/OH-BNNS nanocomposites, whereas the incorporation of a small amount of NH2-BNNSs can cause exclusive formation of polar β- and γ-phases. X-ray photoelectron spectroscopy (XPS) and FTIR reveal that there exists a stronger interaction between PVDF and NH2-BNNSs than that between PVDF and OH-BNNSs in both solid and melt states, which is responsible for the transformation of the crystalline phase and the accelerated crystallization of PVDF/NH2-BNNS nanocomposites.
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Polar crystalline phases of PVDF induced by interaction with functionalized boron nitride nanosheets
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Autor/in / Beteiligte Person: | Wang, Xin ; Hu, Haiqing ; Xu, Jun-Ting ; Zhao, Jian ; Kong, Deyu ; Zong, Lingbo ; Guo, Fuhai ; Li, Feixiang ; Guo, Hongge |
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Zeitschrift: | CrystEngComm, Jg. 22 (2020), S. 6207-6215 |
Veröffentlichung: | Royal Society of Chemistry (RSC), 2020 |
Medientyp: | unknown |
ISSN: | 1466-8033 (print) |
DOI: | 10.1039/d0ce01001d |
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