ChemInform Abstract: A General Method for Synthesis of cis-Dicarbonyl Epoxides Through DBU/LiBr-Cocatalyzed Cyclization of α,β-Dicarbonyl Peroxides
In: ChemInform, Jg. 47 (2016-11-01)
Online
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Zugriff:
A general method for synthesis of cis -dicarbonyl epoxides is developed. The highly diastereoselective cyclization of α,β-dicarbonyl peroxides is achieved by DBU/LiBr cocatalysis. The coordination of lithium ion with two carbonyl groups is proposed for the control of cis selectivity.
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ChemInform Abstract: A General Method for Synthesis of cis-Dicarbonyl Epoxides Through DBU/LiBr-Cocatalyzed Cyclization of α,β-Dicarbonyl Peroxides
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Autor/in / Beteiligte Person: | Li, Zhiping ; Lu, Shenglin ; Bai, Xiaohui ; Zong, Zhenzhen |
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Zeitschrift: | ChemInform, Jg. 47 (2016-11-01) |
Veröffentlichung: | Wiley, 2016 |
Medientyp: | unknown |
ISSN: | 0931-7597 (print) |
DOI: | 10.1002/chin.201649109 |
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