Dye-sensitized solar cell (DSSC) coated with energy down shift layer of nitrogen-doped carbon quantum dots (N-CQDs) for enhanced current density and stability
In: Applied Surface Science, Jg. 483 (2019-07-01), S. 425-431
Online
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Zugriff:
Utilizing ultraviolet light by using Energy Down Shift (EDS) of quantum dots is a recent approach to efficiently utilize a broader spectrum of light, for energy harvesting. Other than higher efficiency, EDS is highly promising for increasing the stability of Dye-Sensitized Solar cells (DSSC); as it decreases the UV degradation of the cell. Previously, heavy metals-based (Cadmium etc) quantum dots are used for the purpose, which are not only toxic but also have less stability and have complicated synthesis methods. To overcome these issues, a thin coating of green emissive Nitrogen-doped Carbon Quantum Dots (N-CQDs) on DSSC, as a stable and efficient EDS layer is proposed here. N-CQDs were synthesized by a scalable, green and facile one-pot hydrothermal pyrolysis of citric acid in presence of nitrogen source, with a production yield of 65%, and quantum yield of 70%. The readily dispersible and highly stable colloid of N-CQDs was coated on the device, and with an optimized thickness, the power conversion efficiency was increased by 10%. This increase was further confirmed by external quantum efficiency (EQE) test, i.e. N-CQDs coated device showed EQE enhancement majorly in the UV spectrum and enhanced stability in UV light was recorded. The transmittance of FTO-glass was increased due to EDS and it also has an antireflection effect, which intern produces a small increase in EQE in the visible spectrum.
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Dye-sensitized solar cell (DSSC) coated with energy down shift layer of nitrogen-doped carbon quantum dots (N-CQDs) for enhanced current density and stability
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Autor/in / Beteiligte Person: | Sung Hoon Jeong ; Maiyalagan, Thandavarayan ; Ali, Mumtaz ; Aima Sameen Anjum ; Riaz, Rabia ; Min Jae Ko ; Lee, Seoyun |
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Zeitschrift: | Applied Surface Science, Jg. 483 (2019-07-01), S. 425-431 |
Veröffentlichung: | Elsevier BV, 2019 |
Medientyp: | unknown |
ISSN: | 0169-4332 (print) |
DOI: | 10.1016/j.apsusc.2019.03.236 |
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