Ligand-centred coupling of the alkynyl radical cations [Mo(CCR)(Ph2PCH2CH2PPh2)(η-C7H7)]+ (R = Ph or Bun: crystal structure of the dimeric product [Mo2(Ph2PCH2CH2PPh2)2(η-C7H7)2(μ-C4R2)][PF6]2 (R = Ph)
In: Journal of Organometallic Chemistry, Jg. 367 (1989-05-01), S. C21- (4S.)
Online
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Zugriff:
The radical cations [Mo(CCR)(dppe)(η-C7H7)]+ (R = Ph or Bun); dppe = Ph2PCH2CH2PPh2) undergo coupling at Cβ of the alkynyl ligand to afford the divinylidene-bridged, dimeric products [Mo2(dppe)2(η-C7H7)2(μ-C4R2)]2+, characterised crystallographically for R = Ph.
Titel: |
Ligand-centred coupling of the alkynyl radical cations [Mo(CCR)(Ph2PCH2CH2PPh2)(η-C7H7)]+ (R = Ph or Bun: crystal structure of the dimeric product [Mo2(Ph2PCH2CH2PPh2)2(η-C7H7)2(μ-C4R2)][PF6]2 (R = Ph)
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Autor/in / Beteiligte Person: | Whiteley, Mark W. ; Beddoes, Roy L. ; Bitcon, Caroline ; Ricalton, Allen |
Link: | |
Zeitschrift: | Journal of Organometallic Chemistry, Jg. 367 (1989-05-01), S. C21- (4S.) |
Veröffentlichung: | Elsevier BV, 1989 |
Medientyp: | unknown |
ISSN: | 0022-328X (print) |
DOI: | 10.1016/0022-328x(89)87064-0 |
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