Z-scheme CdS/CQDs/g-C3N4 composites with visible-near-infrared light response for efficient photocatalytic organic pollutant degradation
In: Science of The Total Environment, Jg. 704 (2020-02-01), S. 135404-135404
Online
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Zugriff:
We have successfully synthesized novel Z-scheme CdS/CQDs/g-C3N4 composites with visible-near-infrared light response for the photocatalytic degradation of rhodamine B (RhB), methylene Blue (MB) and phenol. Based on the energy band matching theory, CdS was coupled with g-C3N4 using carbon quantum dots (CQDs) as the electron mediator to form the Z-scheme heterojunctions through a simple calcination process. Compared with the single-phase and binary composites, the Z-scheme CdS/CQDs/g-C3N4 composites not only exhibited enhanced photocatalytic activity and photostability but also realized near-infrared light response. CQDs, as the electron mediator, can shuttle the electrons in the CdS/CQDs/g-C3N4 interface via the Z-scheme electron transfer pathway, which lead to improvements in charge separation and oxidizability of the composites. The Z-scheme electron transfer was verified using various techniques, including PL, EIS, EPR and transient photocurrent response. The mechanism of Z-scheme charge transfer was also proposed for the improved photocatalytic RhB degradation activity. In addition, CQDs can capture near-infrared light through the upconversion fluorescence property, ameliorating the broad- spectrum photocatalytic competence. Therefore, the Z-scheme heterojunction with visible-near-infrared light response was utilized to improve charge separation, oxidizability and solar energy utilization, as well as to provide new insights for the construction of CQDs-based Z-scheme composites for photocatalysis applications.
Titel: |
Z-scheme CdS/CQDs/g-C3N4 composites with visible-near-infrared light response for efficient photocatalytic organic pollutant degradation
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Autor/in / Beteiligte Person: | Yue, Xiuping ; Li, Yuzhen ; Liu, Zhichao ; Shi, Jianhui ; Feng, Shuting ; Chen, Tian |
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Zeitschrift: | Science of The Total Environment, Jg. 704 (2020-02-01), S. 135404-135404 |
Veröffentlichung: | Elsevier BV, 2020 |
Medientyp: | unknown |
ISSN: | 0048-9697 (print) |
DOI: | 10.1016/j.scitotenv.2019.135404 |
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