Collision‐induced I(2P1/2) emission in argon and xenon
In: The Journal of Chemical Physics, Jg. 67 (1977-07-15), S. 669-673
Online
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Zugriff:
Long range perturbation theory is used to estimate the magnitude of the dipole transition moment leading to iodine 2P1/2 → 2P3/2 emission during a collision with a rare gas atom. The leading term in the induced transition moment varies as R−4 owing to the dipole–quadrupole term in the interaction potential. The two‐body rate coefficient for collision‐induced radiative decay of I 2P1/2 is calculated using approximate model potentials for XeI and ArI. The coefficients are estimated to be 2×10−19 cm3 sec−1 and 6×10−19 cm3 sec−1 for I 2P1/2 in 300 °K Ar and Xe, respectively.
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Collision‐induced I(2P1/2) emission in argon and xenon
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Autor/in / Beteiligte Person: | Krauss, M. ; Julienne, P. S. |
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Zeitschrift: | The Journal of Chemical Physics, Jg. 67 (1977-07-15), S. 669-673 |
Veröffentlichung: | AIP Publishing, 1977 |
Medientyp: | unknown |
ISSN: | 1089-7690 (print) ; 0021-9606 (print) |
DOI: | 10.1063/1.434870 |
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