A novel 1D chain of azido bridged copper(II) with a salen-type di-Schiff base ligand
In: Journal of Molecular Structure, Jg. 1019 (2012-07-01), S. 32-36
Online
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Zugriff:
One new complex of Cu(II), [(CuL)2Cu3(N3)6]n (1) has been synthesized by reacting the “ligand complex”, [CuL] with copper acetate and sodium azide (NaN3) in methanol–water where the di-Schiff base ligand H2L = N,N′-bis(α-methylsalicylidene)-1,3-propanediamine. The X-ray single crystal structural analysis shows that complex 1 consists of an incomplete face-sharing double cube of four Cu(II) ions with the formula of [(CuL)2Cu2(N3)2]2+ which are connected by [Cu(N3)4]2− unit to form a novel 1D chain.
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A novel 1D chain of azido bridged copper(II) with a salen-type di-Schiff base ligand
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Autor/in / Beteiligte Person: | Biswas, Saptarshi ; Ghosh, Ashutosh |
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Zeitschrift: | Journal of Molecular Structure, Jg. 1019 (2012-07-01), S. 32-36 |
Veröffentlichung: | Elsevier BV, 2012 |
Medientyp: | unknown |
ISSN: | 0022-2860 (print) |
DOI: | 10.1016/j.molstruc.2012.03.030 |
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