Reaction of cyclopentadienyllutetium anthracenide with azobenzene. Synthesis and molecular and crystal structure of the binuclear complex [C5H5(THF)Lu(μ−η2:η2−PhN—NPh)]2(THF)2 and its dynamic behavior in solution
In: Russian Chemical Bulletin, Jg. 46 (1997-09-01), S. 1590-1594
Online
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Zugriff:
The reaction of the cyclopentadienyllutetium anthracenide, C5H5Lu(C14H10)2−(THF)2 (1), with azobenzene yielded the [C5H5(THF)Lu(μ−η2:η2−PhN—NPh)]2(THF)2 (2) binuclear complex. The structure of the reaction product was established by X-ray structural analysis. The dynamic behavior of complex2 in a THF-d8 solution was studied by1H NMR spectroscopy in the temperature range of 265–330 K.
Titel: |
Reaction of cyclopentadienyllutetium anthracenide with azobenzene. Synthesis and molecular and crystal structure of the binuclear complex [C5H5(THF)Lu(μ−η2:η2−PhN—NPh)]2(THF)2 and its dynamic behavior in solution
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Autor/in / Beteiligte Person: | Belyakov, Pavel A. ; Lyssenko, K. A. ; Petrov, E. S. ; M. Yu. Antipin ; Roitershtein, Dmitrii M. |
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Zeitschrift: | Russian Chemical Bulletin, Jg. 46 (1997-09-01), S. 1590-1594 |
Veröffentlichung: | Springer Science and Business Media LLC, 1997 |
Medientyp: | unknown |
ISSN: | 1573-9171 (print) ; 1066-5285 (print) |
DOI: | 10.1007/bf02502946 |
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