Effective reinforcement of epoxy composites with hyperbranched liquid crystals grafted on microcrystalline cellulose fibers
In: Journal of Materials Science, Jg. 51 (2016-06-23), S. 8888-8899
Online
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Zugriff:
Interface design plays a crucial role in developing superior mechanical performance of nature fibers/polymer composites (NPC). Herein, microcrystalline cellulose fibers (MCFs), extracted from sisal fibers, were modified by function end-group hyperbranched liquid crystals (HLP) with respect to improve the wettability and interactions between the MCFs and epoxy resin (EP). The HLP that modified MCFs (HLP-MCFs) were studied by Fourier transform infrared spectroscopy, scanning electron microscopy, X-ray photoelectron spectroscopy, X-ray diffraction, and polarizing microscope. The results showed that the MCFs can be successfully modified by the HLP, which would provide strong MCFs/matrix interfacial adhesion. Therefore, the addition of HLP-MCFs was found to produce significant enhancements in the mechanical and thermal properties of EP. In particular, at 1.0 wt% filler loading, the flexural strength, tensile strength, impact strength, and flexural modulus of the HLP-MCFs/EP composites increased by 60, 69, 130, and 192 %, respectively, as well as the glass transition temperature increased by a notable 42.9 °C. It is anticipated that our current work would inform ongoing efforts to exploit more efficient method to overcome the poor nature fiber/polymer adhesion in the interface region and broad implications for the development of the NPC for engineering applications.
Titel: |
Effective reinforcement of epoxy composites with hyperbranched liquid crystals grafted on microcrystalline cellulose fibers
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Autor/in / Beteiligte Person: | Lingyan, Wu ; Pan, Lulu ; Lu, Shaorong ; Luo, Qiyun ; Yuqi, Li ; Jin, Yang ; Song, Laifu |
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Zeitschrift: | Journal of Materials Science, Jg. 51 (2016-06-23), S. 8888-8899 |
Veröffentlichung: | Springer Science and Business Media LLC, 2016 |
Medientyp: | unknown |
ISSN: | 1573-4803 (print) ; 0022-2461 (print) |
DOI: | 10.1007/s10853-016-0136-9 |
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