Linear tunable NIR emission via selective doping of Ni2+ ion into ZnX2O4 (X=Al, Ga, Cr) spinel matrix
In: Ceramics International, Jg. 47 (2021-06-01), S. 17678-17683
Online
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Zugriff:
Adjusted crystal fields can lead to new hybrid materials with promising optical performance. Transition metal ions (TMIs) with d-d electron transitions are sensitive to their surroundings and can be ideal candidates for crystal field research. Herein, we have selected single Ni2+-doped spinel oxide nanocrystals as a model system to systematically explore luminescence mechanisms in different crystal fields. Ni2+-doped ZnAl2O4, ZnGa2O4, and ZnCr2O4 nanospinels with broad near-infrared (NIR) emission bands fully cover the second biological window (1100–1400 nm). We have developed a ZnX2O4 (X = Al, Ga or Cr) (ZXO) spinel framework system using a melting-evaporation procedure, and the whole fabrication period only required 20 min. By changing X ions in the ZXO matrix framework, linear tunable photoluminescence was successfully realized. A sample with a mixed phase of ZnAl2O4 and ZnCr2O4 (ZACO) was also prepared using the same method, and ultrabroadband emissions ranging from 1050-1550 nm were detected. It is valuable to further explore the combinations based on these frameworks to realize tunable emission spectra. Fundamental research on the physical processes will open a new gateway for further research of TMI-doped nanocrystals with promising luminescence properties and broaden the applications to a variety of areas, especially in the biomedical field.
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Linear tunable NIR emission via selective doping of Ni2+ ion into ZnX2O4 (X=Al, Ga, Cr) spinel matrix
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Autor/in / Beteiligte Person: | Jiang, Chun ; Wang, Weirong ; Yu, Guanliang |
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Zeitschrift: | Ceramics International, Jg. 47 (2021-06-01), S. 17678-17683 |
Veröffentlichung: | Elsevier BV, 2021 |
Medientyp: | unknown |
ISSN: | 0272-8842 (print) |
DOI: | 10.1016/j.ceramint.2021.03.087 |
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