Synthesis and Thermal Reduction of Complexes [NiLn][B10H10] (L = DMF, H2O, n = 6; L = N2H4, n = 3): Formation of Solid Solutions Ni3C1 –xВx
In: Russian Journal of Inorganic Chemistry, Jg. 65 (2020), S. 126-132
Online
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Zugriff:
Nickel(II) complexes of the composition [NiLn][B10H10] (L = DMF, H2O, n = 6; L = N2H4, n = 3) have been synthesized and studied. The thermal reduction of the complexes has been studied in the temperature range 20–800°C in air and in an inert atmosphere. Precursor complexes and their reduction products have been identified by elemental analysis, X-ray powder diffraction, and IR spectroscopy. The physicochemical study of the thermolysis product of complex [Ni(DMF)6][B10H10] shows that scarcely studied solid solutions of the composition Ni3C1 –xВx are formed.
Titel: |
Synthesis and Thermal Reduction of Complexes [NiLn][B10H10] (L = DMF, H2O, n = 6; L = N2H4, n = 3): Formation of Solid Solutions Ni3C1 –xВx
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Autor/in / Beteiligte Person: | Retivov, V. M. ; Avdeeva, Varvara V. ; Goeva, Lyudmila V. ; Kuznetsov, N. T. ; Malinina, Elena A. ; Buzanov, G. A. |
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Zeitschrift: | Russian Journal of Inorganic Chemistry, Jg. 65 (2020), S. 126-132 |
Veröffentlichung: | Pleiades Publishing Ltd, 2020 |
Medientyp: | unknown |
ISSN: | 1531-8613 (print) ; 0036-0236 (print) |
DOI: | 10.1134/s0036023620010118 |
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