Copper(I) complex with BINAP and 3,5-dimethylpyrazole: synthesis and photoluminescent properties
In: Mendeleev Communications, Jg. 29 (2019-09-01), S. 570-572
Online
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Zugriff:
A reaction of [Cu(MeCN)4]BF4 with PzH (3,5-dimethylpyrazole) and BINAP [2,20-bis(diphenylphosphino)-1,10-binaphthyl] leads to the formation of mononuclear CuI complex [Cu(PzH)(BINAP)]BF4 containing the molecule of nondeprotonated pyrazole and one BINAP ligand with two phosphorus atoms chelating the metal. This complex exhibits a bright phosphorescence originating from the 3(M+L)LCT state at room temperature. At 77 K, the emission is splitted into two components: 3(M+L)LCT and 3LC transitions.
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Copper(I) complex with BINAP and 3,5-dimethylpyrazole: synthesis and photoluminescent properties
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Autor/in / Beteiligte Person: | Titov, Aleksei A. ; Filippov, Oleg A. ; Shubina, Elena S. ; Smol'yakov, Alexander F. ; Averin, Alexey A. |
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Zeitschrift: | Mendeleev Communications, Jg. 29 (2019-09-01), S. 570-572 |
Veröffentlichung: | Elsevier BV, 2019 |
Medientyp: | unknown |
ISSN: | 0959-9436 (print) |
DOI: | 10.1016/j.mencom.2019.09.031 |
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