ChemInform Abstract: Unexpected Cleavage of the Cpy-CpyBond in the Reaction of 2,2′-Bipyridine N,N′-Diimines with Acetylenes
In: ChemInform, Jg. 46 (2015-02-19)
Online
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Zugriff:
An unusual cleavage of the Cpy–Cpy bond in the reaction of 2,2′-bipyridine N,N′-diimine and its C-methyl substituted derivatives with acetylenes is described. The effect of the solvent on the yield of 7,7′-bipyrazolo[1,5-a]pyridine-2,2′,3,3′-tetracarboxylates and the products of cleavage of the Cpy–Cpy bond has been studied. The mechanism of the cleavage reaction is discussed on the basis of DFT calculations.
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ChemInform Abstract: Unexpected Cleavage of the Cpy-CpyBond in the Reaction of 2,2′-Bipyridine N,N′-Diimines with Acetylenes
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Autor/in / Beteiligte Person: | Aleksey Yu. Vorob’ev ; Borodkin, Gennady I. ; Supranovich, Vyacheslav I. ; Shubin, Vyacheslav G. |
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Zeitschrift: | ChemInform, Jg. 46 (2015-02-19) |
Veröffentlichung: | Wiley, 2015 |
Medientyp: | unknown |
ISSN: | 0931-7597 (print) |
DOI: | 10.1002/chin.201510212 |
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