Assembly of two hybrid organic-inorganic hexatantalate
In: Inorganic Chemistry Communications, Jg. 101 (2019-03-01), S. 6-10
Online
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Zugriff:
Two neutral polyoxotantalates {[CuL]2[Cu(L)2]2[Ta6O19]}·nH2O have been synthesized by conventional reaction conditions, and characterized via different physical methods. Single-crystal X-ray analyses were carried out on {[CuL]2[CuL2]2[Ta6O19]}‧21H2O (L = 1,10-phen, denoted as 1) and the isostructural {[CuL]2[CuL2]2[Ta6O19]}‧20H2O (L′ = 2,2′-bipy, denoted as 2). Both complexes comprise a Lindqvist [Ta6O19]8− hexatantalate which acts as an octadentate ligand to coordinate two [CuL] units and two [CuL2] fragments through six bridging and two terminal oxygen atoms. In addition, the solid-state magnetic susceptibility of 1 and 2 are investigated briefly.
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Assembly of two hybrid organic-inorganic hexatantalate
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Autor/in / Beteiligte Person: | Wang, Guan ; Niu, Jingyang ; Sun, Junjun ; Li, Chen ; Zhang, Dongdi ; Li, Nan ; Ma, Yachun ; Ma, Pengtao |
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Zeitschrift: | Inorganic Chemistry Communications, Jg. 101 (2019-03-01), S. 6-10 |
Veröffentlichung: | Elsevier BV, 2019 |
Medientyp: | unknown |
ISSN: | 1387-7003 (print) |
DOI: | 10.1016/j.inoche.2019.01.004 |
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