Copper(II) assisted hydrolysis of 2,4,6-tris(pyrazol-1-yl)-1,3,5-triazine. Crystal and molecular structure of catena-[CuL(H2O)Cl]n (L=2,4-dione-1,3,5-(1H)-triazin-1-amido)
In: Inorganica Chimica Acta, Jg. 374 (2011-08-01), S. 637-642
Online
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Zugriff:
This article describes the partial hydrolysis of the multidentate ligand 2,4,6-tris(pyrazol-1-yl)-1,3,5-triazine in the presence of copper(II), to give the anionic ligand 2,4-dione-1,3,5-(1H)-triazin-1-amido, which was isolated as the cupric complex catena-[CuL(H2O)Cl]n, where L is the amido ligand. No other hydrolysis products were isolated or identified. The complex defines a zigzag 1D covalent chain, along the b cell axis, through apical copper–oxygen bonds (Cu–N–C–O···Cu bridges).
Titel: |
Copper(II) assisted hydrolysis of 2,4,6-tris(pyrazol-1-yl)-1,3,5-triazine. Crystal and molecular structure of catena-[CuL(H2O)Cl]n (L=2,4-dione-1,3,5-(1H)-triazin-1-amido)
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Autor/in / Beteiligte Person: | Vega, Andrés ; Acuña, Carolina ; Manzur, Jorge ; Ana María García |
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Zeitschrift: | Inorganica Chimica Acta, Jg. 374 (2011-08-01), S. 637-642 |
Veröffentlichung: | Elsevier BV, 2011 |
Medientyp: | unknown |
ISSN: | 0020-1693 (print) |
DOI: | 10.1016/j.ica.2011.03.031 |
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