Product branching ratios in the reaction of Xe*(3P2,0) with IBr. Role of excited potential surface
In: The Journal of Chemical Physics, Jg. 81 (1984-09-01), S. 2352-2356
Online
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Zugriff:
The reaction of Xe*(3P2,0) with IBr to form the XeI* and XeBr* excimers was studied using two crossed molecular beam techniques. Emission spectra were obtained between 200 and 400 nm, and relative cross sections and branching ratios were measured as a function of collision energy over the range 15–420 meV. The observed effects are discussed in terms of a curve crossing model, involving the neutral potential surface and both ground and excited Xe++IBr− potential surfaces. In this model, XeBr* is formed from the ground state ionic potential and XeI* is formed from the excited potential.
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Product branching ratios in the reaction of Xe*(3P2,0) with IBr. Role of excited potential surface
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Autor/in / Beteiligte Person: | Martin, Richard M. ; Tyndall, George W. ; Mattanjah S. de Vries |
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Zeitschrift: | The Journal of Chemical Physics, Jg. 81 (1984-09-01), S. 2352-2356 |
Veröffentlichung: | AIP Publishing, 1984 |
Medientyp: | unknown |
ISSN: | 1089-7690 (print) ; 0021-9606 (print) |
DOI: | 10.1063/1.447934 |
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