Crystal structure of [CuL](NO3)(ReO4) and [CuL](ReO4)2 (L = 4,6,6-trimethyl-1,9-diamino-3,7-diazanon-3-en)
In: Journal of Structural Chemistry, Jg. 53 (2012-02-01), S. 138-144
Online
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Zugriff:
The crystal structures of [CuL](NO3)(ReO4) and [CuL](ReO4)2 (L is 4,6,6-trimethyl-1,9-diamino-3,7-diazanon-3-en) are studied. The square coordination of the copper atom in [CuL](NO3)(ReO4) is completed to a distorted octahedron by two oxygen atoms: Cu…O (ReO4−) 2.393 A and Cu…O (NO3−) 2.685 A, and that in [CuL](ReO4)2, by Cu…O(ReO4−) 2.468 A and 2.697 A. The products of thermolysis of the salts in a hydrogen atmosphere at 800°C are mixtures of nanocrystalline metal powders with coherent scattering regions of ∼45 nm.
Titel: |
Crystal structure of [CuL](NO3)(ReO4) and [CuL](ReO4)2 (L = 4,6,6-trimethyl-1,9-diamino-3,7-diazanon-3-en)
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Autor/in / Beteiligte Person: | Khranenko, S. P. ; Gromilov, S. A. ; Bykova, Elena ; E. Yu. Semitut |
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Zeitschrift: | Journal of Structural Chemistry, Jg. 53 (2012-02-01), S. 138-144 |
Veröffentlichung: | Pleiades Publishing Ltd, 2012 |
Medientyp: | unknown |
ISSN: | 1573-8779 (print) ; 0022-4766 (print) |
DOI: | 10.1134/s0022476612010180 |
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