Nanomorphology and Charge Generation in Bulk Heterojunctions Based on Low-Bandgap Dithiophene Polymers with Different Bridging Atoms
In: Advanced Functional Materials, Jg. 20 (2010-03-29), S. 1180-1188
Online
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Zugriff:
Carbon bridged (C-PCPDTBT) and silicon-bridged (Si-PCPDTBT) dithiophene donor-acceptor copolymers belong to a promising class of low bandgap materials. Their higher field-effect mobility, as high as 10 -2 cm 2 V -1 s -1 in pristine films, and their more balanced charge transport in blends with fullerenes make silicon-bridged materials better candidates for use in photovoltaic devices. Striking morphological changes are observed in polymer:fullerene bulk heterojunctions upon the substitution of the bridging atom. XRD investigation indicates increased π-π stacking in Si-PCPDTBT compared to the carbon-bridged analogue. The fluorescence of this polymer and that of its counterpart C-PCPDTBT indicates that the higher photogeneration achieved in Si-PCPDTBT:fullerene films (with either [C60]PCBM or [C70]PCBM) can be correlated to the inactivation of a charge-transfer complex and to a favorable length of the donor-acceptor phase separation. TEM studies of Si-PCPDTBT:fullerene blended films suggest the formation of an interpenetrating network whose phase distribution is comparable to the one achieved in C-PCPDTBT-fullerene using 1,8-octanedithiol as an additive. In order to achieve a balanced hole and electron transport, Si-PCPDTBT requires a lower fullerene content (between 50 to 60 wt%) than C-PCPDTBT (more than 70 wt%). The Si-PCPDTBT:[C70]PCBM OBHJ solar cells deliver power conversion efficiencies of over 5%.
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Nanomorphology and Charge Generation in Bulk Heterojunctions Based on Low-Bandgap Dithiophene Polymers with Different Bridging Atoms
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Autor/in / Beteiligte Person: | Brabec, Christoph J. ; Scharber, Markus C. ; Hingerl, Kurt ; Gaudiana, Russell ; J Joachim Loos ; Zhu, Zenghuo ; Dennler, Gilles ; Morana, Mauro ; Forberich, Karen ; Waller, David ; Azimi, Hamed ; SS Svetlana van Bavel ; Egelhaaf, Hans-Joachim ; Hauch, Jens ; Materials and Interface Chemistry |
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Zeitschrift: | Advanced Functional Materials, Jg. 20 (2010-03-29), S. 1180-1188 |
Veröffentlichung: | Wiley, 2010 |
Medientyp: | unknown |
ISSN: | 1616-3028 (print) ; 1616-301X (print) |
DOI: | 10.1002/adfm.200900931 |
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