Synthesis and reaction of [(Tp(iPr2))LnH2]3 (Ln = Y, Lu) with CO: trinuclear cluster-bound propenolate en route to selective formation of propene
In: Journal of the American Chemical Society, Jg. 132 (2009-12-18), Heft 1
Online
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Zugriff:
The use of the Tp(iPr(2)) ligand led to the straightforward and high-yield synthesis of rare examples of trinuclear monoligand lanthanide dihydrides, [(Tp(iPr(2)))LnH(2)](3) (Ln = Y, Lu). The Y complex was found to mediate the hydrogenation and coupling of carbon monoxide with exclusive formation of propene via the intermediacy of a cluster-bound propenolate ligand.
Titel: |
Synthesis and reaction of [(Tp(iPr2))LnH2]3 (Ln = Y, Lu) with CO: trinuclear cluster-bound propenolate en route to selective formation of propene
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Autor/in / Beteiligte Person: | Ferguson, Michael J. ; Cheng, Jianhua ; Takats, Josef |
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Zeitschrift: | Journal of the American Chemical Society, Jg. 132 (2009-12-18), Heft 1 |
Veröffentlichung: | 2009 |
Medientyp: | unknown |
ISSN: | 1520-5126 (print) |
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