N-heterocyclic silylene stabilized monocordinated copper(i)-arene cationic complexes and their application in click chemistry
In: Chemical communications (Cambridge, England), Jg. 56 (2019-12-07), Heft 2
Online
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Zugriff:
Herein for the first time we report monocoordinated cationic Cu(I) complexes with unsymmetrical arenes (toluene and m-xylene) [LCu(η3-C7H8)]+[SbF6]− and [{LCu(η2-Me2C6H4)}]+[SbF6]− [L = {PhC(NtBu)2SiN(SiMe3)2}], [IPr (1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)], their reactivity and catalytic applications in CuAAC reactions (12 examples). The bonding analysis was performed in both silylene and carbene complexes using the EDA-NOCV method at the BP86/TZ2P level of theory.
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N-heterocyclic silylene stabilized monocordinated copper(i)-arene cationic complexes and their application in click chemistry
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Autor/in / Beteiligte Person: | Parameswaran, Pattiyil ; Parvin, Nasrina ; George, Anjana ; Khan, Shabana ; Hossain, Jabed |
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Zeitschrift: | Chemical communications (Cambridge, England), Jg. 56 (2019-12-07), Heft 2 |
Veröffentlichung: | 2019 |
Medientyp: | unknown |
ISSN: | 1364-548X (print) |
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