Hierarchically porous materials: synthesis strategies and structure design
In: Chemical Society Reviews, Jg. 46 (2017), S. 481-558
Online
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Zugriff:
Owing to their immense potential in energy conversion and storage, catalysis, photocatalysis, adsorption, separation and life science applications, significant interest has been devoted to the design and synthesis of hierarchically porous materials. The hierarchy of materials on porosity, structural, morphological, and component levels is key for high performance in all kinds of applications. Synthesis and applications of hierarchically structured porous materials have become a rapidly evolving field of current interest. A large series of synthesis methods have been developed. This review addresses recent advances made in studies of this topic. After identifying the advantages and problems of natural hierarchically porous materials, synthetic hierarchically porous materials are presented. The synthesis strategies used to prepare hierarchically porous materials are first introduced and the features of synthesis and the resulting structures are presented using a series of examples. These involve templating methods (surfactant templating, nanocasting, macroporous polymer templating, colloidal crystal templating and bioinspired process, i.e. biotemplating), conventional techniques (supercritical fluids, emulsion, freeze-drying, breath figures, selective leaching, phase separation, zeolitization process, and replication) and basic methods (sol-gel controlling and post-treatment), as well as self-formation phenomenon of porous hierarchy. A series of detailed examples are given to show methods for the synthesis of hierarchically porous structures with various chemical compositions (dual porosities: micro-micropores, micro-mesopores, micro-macropores, meso-mesopores, meso-macropores, multiple porosities: micro-meso-macropores and meso-meso-macropores). We hope that this review will be helpful for those entering the field and also for those in the field who want quick access to helpful reference information about the synthesis of new hierarchically porous materials and methods to control their structure and morphology.
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Hierarchically porous materials: synthesis strategies and structure design
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Autor/in / Beteiligte Person: | Su, Bao-Lian ; Rooke, Joanna C. ; Yang, Xiao-Yu ; Chen, Li-Hua ; Sanchez, Clément ; Li, Yu ; State key Laboratory of Advanced Technology for Materials Synthesis and Processing ; WUHAN UNIVERSITY OF, TECHNOLOGY ; Université de Namur [Namur] (UNamur) ; Matériaux Hybrides et Nanomatériaux (MHN) ; Laboratoire de Chimie de la Matière Condensée de Paris (LCMCP) ; Université Pierre et Marie Curie - Paris 6 (UPMC)-Collège de France (CdF (institution))-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Collège de France (CdF (institution))-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS) ; Chaire Chimie des matériaux hybrides ; Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS) ; University of Cambridge [UK] (CAM) ; Wuhan University of Technology (WHUT) |
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Zeitschrift: | Chemical Society Reviews, Jg. 46 (2017), S. 481-558 |
Veröffentlichung: | Royal Society of Chemistry (RSC), 2017 |
Medientyp: | unknown |
ISSN: | 1460-4744 (print) ; 0306-0012 (print) |
DOI: | 10.1039/c6cs00829a |
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