The influence of textural and structural properties of Pd/carbon on the hydrogenation of cis,trans,trans-1,5,9-cyclododecatriene
In: Applied Catalysis A: General, Jg. 318 (2007-02-01), S. 17-21
Online
unknown
Zugriff:
International audience; Carbon-supported palladium catalysts were prepared by ion-exchange and precipitation/deposition methods on various activated carbons. Pd/carbon catalysts with Pd particles ranging from 1.5 to 10 nm were thus obtained. The liquid phase hydrogenation of c,t,t-1,5,9-cyclododecatriene was carried out on these catalysts. A structure-sensitivity was observed with a decrease of TOF on smallest Pd particles. The highest yield to halfhydrogenated cyclododecene was observed on large Pd particles (10 nm).
| Titel: |
The influence of textural and structural properties of Pd/carbon on the hydrogenation of cis,trans,trans-1,5,9-cyclododecatriene
|
|---|---|
| Autor/in / Beteiligte Person: | Delahay, Gérard ; Medevielle, Alice ; Durand, Robert ; Coq, Bernard ; Plee, Dominique ; Trens, Philippe ; Cabiac, Amandine ; Laboratoire de Matériaux Catalytiques et Catalyse en Chimie Organique (LMCCCO) ; Université Montpellier 1 (UM1)-Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Centre National de la Recherche Scientifique (CNRS) ; Groupement de Recherches de Lacq ; (Arkema), Arkema ; S.A, CECA |
| Link: | |
| Zeitschrift: | Applied Catalysis A: General, Jg. 318 (2007-02-01), S. 17-21 |
| Veröffentlichung: | Elsevier BV, 2007 |
| Medientyp: | unknown |
| ISSN: | 0926-860X (print) |
| DOI: | 10.1016/j.apcata.2006.10.033 |
| Schlagwort: |
|
| Sonstiges: |
|