Magnetic and structural properties of pure and Cr-doped haematite: α-Fe2−xCr x O3 (0 ≤ x ≤ 1)
In: Journal of Advanced Ceramics, Jg. 2 (2013-12-01), S. 360-369
Online
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Zugriff:
Solid-state ceramic technique route is used for synthesizing Cr-doped haematite α-Fe2−xCr x O3 (x = 0, 0.125, 0.50 and 1) samples. Single phase and corundum (Al2O3) type structure is revealed from the X-ray diffraction (XRD) patterns. The Raman spectra of α-Fe2−xCr x O3 illustrate seven phonon modes. On substitution of Cr (x = 0, 0.125, 0.50 and 1) at Fe site, all Raman active modes are shifted to higher wave numbers. The coercivity and remanence of Cr-doped haematites increase as x increases. The increased coercivity and remanence for Cr-doped samples can be attributed to their enhanced shape and magneto-crystalline anisotropy. The observed isomer shift δ values from room-temperature Mossbauer data clearly show the presence of ferric (Fe3+) and Cr3+ ions illustrating strong ferromagnetic ordering up to x = 0.125 in α-Fe2−xCr x O3 haematite and weak ferromagnetic ordering for α-Fe2−xCr x O3 (x > 0.125) haematites.
Titel: |
Magnetic and structural properties of pure and Cr-doped haematite: α-Fe2−xCr x O3 (0 ≤ x ≤ 1)
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Autor/in / Beteiligte Person: | Yogi, A. ; Varshney, Dinesh |
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Zeitschrift: | Journal of Advanced Ceramics, Jg. 2 (2013-12-01), S. 360-369 |
Veröffentlichung: | Tsinghua University Press, 2013 |
Medientyp: | unknown |
ISSN: | 2227-8508 (print) ; 2226-4108 (print) |
DOI: | 10.1007/s40145-013-0084-7 |
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