Carbohydrate/DBU Cocatalyzed Alkene Diboration: Mechanistic Insight Provides Enhanced Catalytic Efficiency and Substrate Scope
In: Journal of the American Chemical Society, Jg. 140 (2018-02-15), Heft 10
Online
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Zugriff:
A mechanistic investigation of the carbohydrate/DBU co-catalyzed enantioselective diboration of alkenes is presented. These studies provide an understanding of the origin of stereoselectivity and also reveal a strategy for enhancing reactivity and broadening the substrate scope.
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Carbohydrate/DBU Cocatalyzed Alkene Diboration: Mechanistic Insight Provides Enhanced Catalytic Efficiency and Substrate Scope
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Autor/in / Beteiligte Person: | Morken, James P. ; Meng, Yan ; Yan, Lu ; Crockett, Michael P. ; Leon, Robert M. ; Haeffner, Fredrik |
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Zeitschrift: | Journal of the American Chemical Society, Jg. 140 (2018-02-15), Heft 10 |
Veröffentlichung: | 2018 |
Medientyp: | unknown |
ISSN: | 1520-5126 (print) |
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