Synthesis, crystal structures and antibacterial activities of trifluoromethylsulfonate salts of 2-[(3-chloropyridinium-2-yl)hydrazonomethyl]-6-methoxyphenol and its copper(II) and cobalt(III) complexes
In: Acta Chimica Slovenica, Jg. 63 (2016), Heft 4, S. 856-863
Online
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Zugriff:
A new trifluoromethylsulfonate salt of 2-[(3-chloropyridinium-2-yl)hydrazonomethyl]-6-methoxyphenol, (HL)CF 3 SO 3 , and its copper(II) and cobalt(III) complexes, [CuL(OH 2 )]CF 3 SO 3 ·0.5H 2 O ( 1 ) and [CoL 2 ]CF 3 SO 3 ·CH 3 OH ( 2 ), were prepared and characterized by physico-chemical methods and single crystal X-ray analysis. A trifluoromethylsulfonate anion is present in each of the compounds. The Cu atom in complex 1 is coordinated by the phenolate O, imino N and pyridine N atoms of L ligand, giving square planar geometry. The Co atom in complex 2 is coordinated by two phenolate O, two imino N and two pyridine N atoms from two L ligands, giving octahedral geometry. The three compounds were tested in vitro for their antibacterial activities.
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Synthesis, crystal structures and antibacterial activities of trifluoromethylsulfonate salts of 2-[(3-chloropyridinium-2-yl)hydrazonomethyl]-6-methoxyphenol and its copper(II) and cobalt(III) complexes
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Autor/in / Beteiligte Person: | Sun, Wei-Dong ; Lin, Xue-Song ; Sang, Ya-Li |
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Zeitschrift: | Acta Chimica Slovenica, Jg. 63 (2016), Heft 4, S. 856-863 |
Veröffentlichung: | Slovenian Chemical Society, 2016 |
Medientyp: | unknown |
ISSN: | 1580-3155 (print) ; 1318-0207 (print) |
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