Metal–organic frameworks meet polymer brushes: enhanced crystalline film growth induced by macromolecular primers
In: Materials Chemistry Frontiers, Jg. 1 (2017), S. 2256-2260
Online
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Zugriff:
We used poly-(3-sulfopropylmethacrylate) brushes as macromolecular 3D primers to promote heterogeneous nucleation and growth of archetypal ZIF-8 MOF thin films. The enhancement can be understood in terms of a high preconcentration of Zn2+ ions in the polymer brush; this leads to a rapid increase of nucleation sites in the primer.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas
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Metal–organic frameworks meet polymer brushes: enhanced crystalline film growth induced by macromolecular primers
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Autor/in / Beteiligte Person: | Azzaroni, Omar ; Giussi, Juan M. ; Juan A Allegretto ; Bindini, Elisa ; Jimena Soledad Tuninetti ; Rafti, Matías ; Segovia, Gustavo M. ; Universidad Nacional de la Plata [Argentine] (UNLP) ; Universidad Nacional de San Martin (UNSAM) ; Matériaux Hybrides et Nanomatériaux (MHN) ; Laboratoire de Chimie de la Matière Condensée de Paris (LCMCP) ; Université Pierre et Marie Curie - Paris 6 (UPMC)-Collège de France (CdF (institution))-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Collège de France (CdF (institution))-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS) ; Université Pierre et Marie Curie - Paris 6 (UPMC)-Centre National de la Recherche Scientifique (CNRS)-Collège de France (CdF (institution))-Institut de Chimie du CNRS (INC)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Centre National de la Recherche Scientifique (CNRS)-Collège de France (CdF (institution))-Institut de Chimie du CNRS (INC) |
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Zeitschrift: | Materials Chemistry Frontiers, Jg. 1 (2017), S. 2256-2260 |
Veröffentlichung: | Royal Society of Chemistry (RSC), 2017 |
Medientyp: | unknown |
ISSN: | 2052-1537 (print) |
DOI: | 10.1039/c7qm00235a |
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