A novel meso-tetrakis(2,4,6-trimethylphenyl) porphyrinato ([Zn(TMP)(4,4′-bpy)]) complex: Synthesis, characterization, and application
In: Inorganic Chemistry Communications Inorganic Chemistry Communications, Elsevier, 2021, 130, pp.108716. ⟨10.1016/j.inoche.2021.108716⟩; (2021-08-01)
Online
unknown
Zugriff:
A new metalloporphyrin (4,4′-bipyridine)meso-tetrakis(2,4,6-trimethylphenyl) porphyrinato) zinc(II) ([Zn(TMP)(4,4′-bpy)]) (3) was obtained by reacting meso-tetrakis(2,4,6-trimethylphenyl)porphyrinato) zinc(II) [Zn(TMP)] (2) and 4,4′-bipyridine (4,4′-bpy). The starting material meso-tetrakis(2,4,6-trimethylphenyl)porphyrine (H2TMP, 1) as well as complexes (2 and 3) were characterized by the means of microanalysis, 1H NMR, and ESI-MS techniques. The molecular structure of the final complex (3) was also confirmed by single crystal X-ray crystallography. Detailed photo-physical and electrochemical properties of the complexes were also determined. The oxidative degradation ability of complexes (2 and 3) was evaluated and compared against an organic dye (calmagite). When used as catalyst, complex (2) showed better efficiency ~ 48% than the complex (3) (41%). Overall, this work not only explores the ability of metalloporphyrin to degrade organic dyes in aqueous solution, but also showed that the degradation ability of a metalloporphyrin complex can be fine-tuned by varying axial ligand.
| Titel: |
A novel meso-tetrakis(2,4,6-trimethylphenyl) porphyrinato ([Zn(TMP)(4,4′-bpy)]) complex: Synthesis, characterization, and application
|
|---|---|
| Autor/in / Beteiligte Person: | Soury, Raoudha ; Alenezi, Khalaf M. ; Solladié, Nathalie ; Jabli, Mahjoub ; Hani El Moll ; Haque, Ashanul ; Chaabene, Marwa ; Rein, Régis ; Eid M.S. Azzam ; University of Hail ; University, Majmaah ; Laboratoire des Interfaces et Matériaux Avancés [Monastir] (LIMA) ; Faculté des Sciences de Monastir (FSM) ; Université de Monastir - University of Monastir (UM)-Université de Monastir - University of Monastir (UM) ; Laboratoire de chimie de coordination (LCC) ; Institut National Polytechnique (Toulouse) (Toulouse INP) ; Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Université Toulouse III - Paul Sabatier (UT3) ; Université Fédérale Toulouse Midi-Pyrénées-Institut de Chimie de Toulouse (ICT-FR 2599) ; Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Université Toulouse III - Paul Sabatier (UT3) ; Université Fédérale Toulouse Midi-Pyrénées-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS) |
| Link: | |
| Quelle: | Inorganic Chemistry Communications Inorganic Chemistry Communications, Elsevier, 2021, 130, pp.108716. ⟨10.1016/j.inoche.2021.108716⟩; (2021-08-01) |
| Veröffentlichung: | HAL CCSD, 2021 |
| Medientyp: | unknown |
| ISSN: | 1387-7003 (print) |
| Schlagwort: |
|
| Sonstiges: |
|