Multicomponent new particle formation from sulfuric acid, ammonia, and biogenic vapors
In: Science Advances Science Advances, 2018, 4 (12), pp.eaau5363. ⟨10.1126/sciadv.aau5363⟩ Science Advances, American Association for the Advancement of Science (AAAS), 2018, 4 (12), pp.eaau5363. ⟨10.1126/sciadv.aau5363⟩ Lehtipalo, K, Yan, C, Dada, L, Bianchi, F, Xiao, M, Wagner, R, Stolzenburg, D, Ahonen, L R, Amorim, A, Baccarini, A, Bauer, P S, Baumgartner, B, Bergen, A, Bernhammer, A K, Breitenlechner, M, Brilke, S, Buchholz, A, Mazon, S B, Chen, D, Chen, X, Dias, A, Dommen, J, Draper, D C, Duplissy, J, Ehn, M, Finkenzeller, H, Fischer, L, Frege, C, Fuchs, C, Garmash, O, Gordon, H, Hakala, J, He, X, Heikkinen, L, Heinritzi, M, Helm, J C, Hofbauer, V, Hoyle, C R, Jokinen, T, Kangasluoma, J, Kerminen, V M, Kim, C, Kirkby, J, Kontkanen, J, Kürten, A, Lawler, M J, Mai, H, Mathot, S, Mauldin, R L, Molteni, U, Nichman, L, Nie, W, Nieminen, T, Ojdanic, A, Onnela, A, Passananti, M, Petäjä, T, Piel, F, Pospisilova, V, Quéléver, L L J, Rissanen, M P, Rose, C, Sarnela, N, Schallhart, S, Schuchmann, S, Sengupta, K, Simon, M, Sipilä, M, Tauber, C, Tomé, A, Tröstl, J, Väisänen, O, Vogel, A L, Volkamer, R, Wagner, A C, Wang, M, Weitz, L, Wimmer, D, Ye, P, Ylisirniö, A, Zha, Q, Carslaw, K S, Curtius, J, Donahue, N M, Flagan, R C, Hansel, A, Riipinen, I, Virtanen, A, Winkler, P M, Baltensperger, U, Kulmala, M & Worsnop, D R 2018, ' Multicomponent new particle formation from sulfuric acid, ammonia, and biogenic vapors ', Science advances, vol. 4, no. 12, eaau5363 https://doi.org/10.1126/sciadv.aau5363; (2018-12-12)
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Zugriff:
Atmospheric aerosol formation from biogenic vapors is strongly affected by air pollutants, like NOx, SO2, and NH3.
A major fraction of atmospheric aerosol particles, which affect both air quality and climate, form from gaseous precursors in the atmosphere. Highly oxygenated organic molecules (HOMs), formed by oxidation of biogenic volatile organic compounds, are known to participate in particle formation and growth. However, it is not well understood how they interact with atmospheric pollutants, such as nitrogen oxides (NOx) and sulfur oxides (SOx) from fossil fuel combustion, as well as ammonia (NH3) from livestock and fertilizers. Here, we show how NOx suppresses particle formation, while HOMs, sulfuric acid, and NH3 have a synergistic enhancing effect on particle formation. We postulate a novel mechanism, involving HOMs, sulfuric acid, and ammonia, which is able to closely reproduce observations of particle formation and growth in daytime boreal forest and similar environments. The findings elucidate the complex interactions between biogenic and anthropogenic vapors in the atmospheric aerosol system.
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Multicomponent new particle formation from sulfuric acid, ammonia, and biogenic vapors
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| Autor/in / Beteiligte Person: | Dada, Lubna ; Rose, Clémence ; Tomé, António ; Carslaw, Kenneth S. ; Worsnop, Douglas R. ; Sarnela, Nina ; Kangasluoma, Juha ; Kulmala, Markku ; Paulus Salomon Bauer ; Curtius, Joachim ; Winkler, Paul M. ; Hofbauer, Victoria ; Ahonen, Lauri ; Chen, Dexian ; Schallhart, Simon ; Tröstl, Jasmin ; Molteni, Ugo ; Onnela, Antti ; Ylisirniö, Arttu ; Dommen, Josef ; Brilke, Sophia ; Simon, Mario ; Yan, Chao ; Nichman, Leonid ; Donahue, Neil M. ; Mai, Huajun ; Pospisilova, Veronika ; Kirkby, Jasper ; Duplissy, Jonathan ; Nieminen, Tuomo ; Ye, Penglin ; Wimmer, Daniela ; Ehn, Mikael ; Tauber, Christian ; Hakala, Jani ; Mauldin, Roy L. ; Rissanen, Matti P. ; Weitz, Lena ; Kontkanen, Jenni ; Vogel, Alexander L. ; Stephany Buenrostro Mazon ; Breitenlechner, Martin ; He, Xucheng ; Baltensperger, Urs ; Stolzenburg, Dominik ; Draper, Danielle C. ; Kim, Changhyuk ; Riipinen, Ilona ; Wagner, Robert ; Fischer, Lukas ; Virtanen, Annele ; Helm, Johanna ; Kürten, Andreas ; Chen, Xuemeng ; Volkamer, Rainer ; Piel, Felix ; Garmash, Olga ; Frege, Carla ; Buchholz, Angela ; Jokinen, Tuija ; Xiao, Mao ; Nie, Wei ; Hansel, Armin ; Baccarini, Andrea ; Sengupta, Kamalika ; Bernhammer, Anne-Kathrin ; Baumgartner, Bernhard ; Amorim, António ; Wang, Mingyi ; Lawler, Michael J. ; Passananti, Monica ; Heinritzi, Martin ; Väisänen, Olli ; Fuchs, Claudia ; Sipilä, Mikko ; Petäjä, Tuukka ; Schuchmann, Simone ; Hoyle, Christopher R. ; Andrea Christine Wagner ; Lehtipalo, Katrianne ; Finkenzeller, Henning ; Dias, A.A. ; Zha, Qiaozhi ; Mathot, Serge ; Gordon, Hamish ; Quéléver, Lauriane L. J. ; Heikkinen, Liine ; Kerminen, Veli-Matti ; Ojdanic, Andrea ; Bergen, Anton ; Bianchi, F. ; Flagan, Richard C. ; Paul Scherrer Institute (PSI) ; Helsingin yliopisto = Helsingfors universitet = University of Helsinki ; Finnish Meteorological Institute (FMI) ; University of Vienna [Vienna] ; Universidade de Lisboa = University of Lisbon (ULISBOA) ; Institute for Atmospheric and Environmental Sciences [Frankfurt/Main] (IAU) ; Goethe-University Frankfurt am Main ; GesmbH, Ionicon ; Institut für Ionenphysik und Angewandte Physik - Institute for Ion Physics and Applied Physics [Innsbruck] ; Leopold Franzens Universität Innsbruck - University of Innsbruck ; University of Eastern Finland ; Carnegie Mellon University [Pittsburgh] (CMU) ; University of California [Irvine] (UC Irvine) ; University of California (UC) ; University of Colorado [Boulder] ; University of Leeds ; Institut für Atmosphäre und Umwelt [Frankfurt/Main] (IAU) ; Goethe-Universität Frankfurt am Main ; California Institute of Technology (CALTECH) ; Pusan National University ; CERN [Genève] ; University, Stockholm ; School of Earth and Environmental Sciences [Manchester] (SEES) ; University of Manchester [Manchester] ; Boston College (BC) ; Nanjing University (NJU) ; Laboratory of Atmospheric Chemistry [Paul Scherrer Institute] (LAC) ; Laboratoire de Météorologie Physique (LaMP) ; Institut national des sciences de l'Univers (INSU - CNRS)-Université Clermont Auvergne [2017-2020] (UCA [2017-2020])-Centre National de la Recherche Scientifique (CNRS) ; University of Beira Interior [Portugal] (UBI) ; Aerodyne Research Inc. ; University, Tempere ; Institute for Atmospheric and Earth System Research (INAR) ; Physics, INAR ; Aerosol-Cloud-Climate -Interactions (ACCI) ; Helsinki Institute of Physics ; Polar and arctic atmospheric research (PANDA) ; University of Helsinki ; Universidade de Lisboa (ULISBOA) ; University of California [Irvine] (UCI) ; University of California ; University, Tampere ; Physics |
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| Quelle: | Science Advances Science Advances, 2018, 4 (12), pp.eaau5363. ⟨10.1126/sciadv.aau5363⟩ Science Advances, American Association for the Advancement of Science (AAAS), 2018, 4 (12), pp.eaau5363. ⟨10.1126/sciadv.aau5363⟩ Lehtipalo, K, Yan, C, Dada, L, Bianchi, F, Xiao, M, Wagner, R, Stolzenburg, D, Ahonen, L R, Amorim, A, Baccarini, A, Bauer, P S, Baumgartner, B, Bergen, A, Bernhammer, A K, Breitenlechner, M, Brilke, S, Buchholz, A, Mazon, S B, Chen, D, Chen, X, Dias, A, Dommen, J, Draper, D C, Duplissy, J, Ehn, M, Finkenzeller, H, Fischer, L, Frege, C, Fuchs, C, Garmash, O, Gordon, H, Hakala, J, He, X, Heikkinen, L, Heinritzi, M, Helm, J C, Hofbauer, V, Hoyle, C R, Jokinen, T, Kangasluoma, J, Kerminen, V M, Kim, C, Kirkby, J, Kontkanen, J, Kürten, A, Lawler, M J, Mai, H, Mathot, S, Mauldin, R L, Molteni, U, Nichman, L, Nie, W, Nieminen, T, Ojdanic, A, Onnela, A, Passananti, M, Petäjä, T, Piel, F, Pospisilova, V, Quéléver, L L J, Rissanen, M P, Rose, C, Sarnela, N, Schallhart, S, Schuchmann, S, Sengupta, K, Simon, M, Sipilä, M, Tauber, C, Tomé, A, Tröstl, J, Väisänen, O, Vogel, A L, Volkamer, R, Wagner, A C, Wang, M, Weitz, L, Wimmer, D, Ye, P, Ylisirniö, A, Zha, Q, Carslaw, K S, Curtius, J, Donahue, N M, Flagan, R C, Hansel, A, Riipinen, I, Virtanen, A, Winkler, P M, Baltensperger, U, Kulmala, M & Worsnop, D R 2018, ' Multicomponent new particle formation from sulfuric acid, ammonia, and biogenic vapors ', Science advances, vol. 4, no. 12, eaau5363 https://doi.org/10.1126/sciadv.aau5363; (2018-12-12) |
| Veröffentlichung: | American Association for the Advancement of Science, 2018 |
| Medientyp: | unknown |
| ISSN: | 2375-2548 (print) |
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