Synthesis of Amylose-b-P2VP Block Copolymers
In: Macromolecular Rapid Communications, Jg. 36 (2015-10-05), S. 2097-2101
Online
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Zugriff:
A new class of rod-coil block copolymers is synthesized by chemoenzymatic polymerization. In the first step, maltoheptaose, which acts as a primer for the synthesis of amylose, is attached to poly(2-vinyl pyridine) (P2VP). The enzymatic polymerization of maltoheptaose is carried out by phosphorylase to obtain amylose-b-P2VP block copolymers. The block copolymer is characterized by Fourier transform infrared spectroscopy, nuclear magnetic resonance, gel permeation chromatography, and wide-angle X-ray scattering techniques. The designed molecules combine the inclusion complexation ability of amylose with the supramolecular complexation ability of P2VP and therefore this kind of rod-coil block copolymers can be used to generate well-organized novel self-assembled structures.
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Synthesis of Amylose-b-P2VP Block Copolymers
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Autor/in / Beteiligte Person: | Kumar, Kamlesh ; Loos, Katja ; Woortman, Albert J. J. ; Polymers at Surfaces and Interfaces ; Macromolecular Chemistry & New Polymeric Materials |
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Zeitschrift: | Macromolecular Rapid Communications, Jg. 36 (2015-10-05), S. 2097-2101 |
Veröffentlichung: | Wiley, 2015 |
Medientyp: | unknown |
ISSN: | 1022-1336 (print) |
DOI: | 10.1002/marc.201500343 |
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