Synthesis and Structures of [LCu(I)(SSiiPr3)] (L = triphos, carbene) and Related Compounds
In: Inorganic Chemistry, Jg. 55 (2016-08-31), S. 9173-9177
Online
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Zugriff:
The mononuclear Cu(I) complexes [LCu(I)(SSi(i)Pr3)] (L = 1,1,1-tris(diphenylphosphinomethyl)ethane (triphos), 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (IMes)) have been prepared by ligand displacement from [LCu(I)Cl] with (i)Pr3SiS(-). Both compounds are colorless, diamagnetic species and have been characterized structurally by X-ray crystallography. The compounds [(IMes)Cu(η(1)κ(S)-SC(O)CH3)] and [(triphos)Cu(η(1)κ(S)-SC(S)OCH3)] have been prepared in the context of synthesis aimed at [LCu(η(1)κ(S)-SCOS)] and [LCu(η(1)κ(S)-SCS2)] complexes, which are intended as synthons toward an analogue of the Mo(μ-OSCO)Cu intermediate proposed as occurring in the catalytic cycle of carbon monoxide dehydrogenase (CODH).
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Synthesis and Structures of [LCu(I)(SSiiPr3)] (L = triphos, carbene) and Related Compounds
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Autor/in / Beteiligte Person: | Mague, Joel T. ; Ferrara, Skylar J. ; Karry Wright LeBlanc ; Wang, Bo ; Donahue, James P. ; Haas, Elaine |
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Zeitschrift: | Inorganic Chemistry, Jg. 55 (2016-08-31), S. 9173-9177 |
Veröffentlichung: | American Chemical Society (ACS), 2016 |
Medientyp: | unknown |
ISSN: | 1520-510X (print) ; 0020-1669 (print) |
DOI: | 10.1021/acs.inorgchem.5b02811 |
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