Sinteza 4-heteroaril substituiranih pirimidinov in njihovih koordinacijskih spojin
2021
Online
unknown
Zugriff:
Sintetizirana je bila serija substituiranih pirimidinov iz acetil heteroaromatov, nato je bila izvedena metilacija pripravljenih spojin. Pri tem je prišlo do nastanka dveh različnih tipov produktov. Vse pripravljene spojine so bile uporabljene kot ligandi za sintezo renijevih koordinacijskih spojin. Vsi produkti so bili karakterizirani z jedrsko magnetno resonanco (NMR), masno spektrometrijo, IR spektroskopijo in elementno analizo CHN. Pripravljeni so bili tudi monokristali nekaterih spojin, katerim je bila določena struktura z rentgensko difrakcijo. A series of substituted pyrimidines were synthesized from acetyl substituted heteroaromatics. Methylation of the prepared compounds was then carried out and two different types of products were isolated. All the prepared compounds were used as ligands in the synthesis of rhenium coordination compounds. All products were characterized by nuclear magnetic resonance (NMR), mass spectrometry, IR spectroscopy and elemental analysis CHN. For some compounds, monocrystals were obtained and their molecular structures were determined by X-ray diffraction.
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Sinteza 4-heteroaril substituiranih pirimidinov in njihovih koordinacijskih spojin
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Autor/in / Beteiligte Person: | Rapuš, Uroš ; Kljun, Jakob |
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Veröffentlichung: | 2021 |
Medientyp: | unknown |
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